Experimental Study of Cohesive Non-swelling Soil Stabilized with Hydroxy-Aluminum Solution for the Treatment of Expansive Soil

SHE Jian-bo, LI Shuai, TANG You-sheng, XIAN Shao-hua, LU Zheng, YAO Hai-lin, ZHOU Yong-wei

Journal of Changjiang River Scientific Research Institute ›› 2025, Vol. 42 ›› Issue (9) : 131-138.

PDF(7524 KB)
PDF(7524 KB)
Journal of Changjiang River Scientific Research Institute ›› 2025, Vol. 42 ›› Issue (9) : 131-138. DOI: 10.11988/ckyyb.20240765
Rock Soil Engineering

Experimental Study of Cohesive Non-swelling Soil Stabilized with Hydroxy-Aluminum Solution for the Treatment of Expansive Soil

Author information +
History +

Abstract

[Objective] Cohesive non-swelling soil (CNS) covering technology, when applied to the in-situ treatment of expansive soil foundations and slopes, frequently necessitates the modification of the expansive soil with traditional additives like lime to prepare suitable CNS materials. Research on the treatment of expansive soil using hydroxy-aluminum remains limited, and its application as an in-situ CNS material has not yet been reported. This study aims to ascertain the viability of using chemically stabilized soil (CSS) with hydroxy-aluminum solution as a CNS cushion layer material through laboratory experiments. [Methods] A series of basic physical-mechanical, chemical, and microstructural tests were carried out. Changes in particle size distribution, Atterberg limits, and compaction indices of soils were analyzed to evaluate the modification effect of hydroxy-aluminum on expansive soil. Subsequently, the permeability, shear strength, and swelling characteristics of the expansive soil (ES), CSS, and CNS were investigated under varying degrees of compaction (85%, 90%, 95%, 100%). Ion concentration analysis of soils and microstructural analyses (XRD, SEM) were also conducted to assess the overall performance of CSS and validate its potential as a CNS cushion layer material. [Results] (1) Following the addition of the hydroxy-aluminum solution, flocculation and agglomeration occurred between the hydroxy-aluminum and the clay particles of expansive soil. This process resulted in a reduction in the dispersibility and hydrophilicity of expansive soil, leading to denser particle packing. Consequently, the particle size distribution of expansive soil shifted, with an increase in silt content from 31% to approximately 46%, and a decrease in clay content from 65% to 51%, indicating a trend toward silty soil. (2) Plasticity index exhibited a substantial decrease, with a 43.5% reduction from 38.06 to 21.49. This decline resulted in a transformation of the soil classification from high-liquid-limit clay (CH) to low-liquid-limit clay (CL). These changes demonstrated a marked improvement in the basic physical properties of expansive soil. (3) Under varying degrees of compaction, the CSS exhibited substantial improvements in permeability, shear strength, and swelling characteristics compared to expansive soil. The permeability coefficient increased from 10-8 to 10-9 cm/s to the order of 10-7 cm/s, reaching a level comparable to that observed in the CNS. The shear strength parameters were enhanced; notably, at high compaction degree (K=100%), the shear strength of CSS even exceeded that of CNS. The swelling potential of CSS was significantly reduced, with the development of swelling deformation following the same trend as CNS. The swelling percentage decreased from 16%-24% to 8%-15%, representing a reduction of 37.5%-50%, which was slightly higher than CNS but still within the range of non-swelling soil. [Conclusion] Overall, the comprehensive performance of CSS was found to be essentially equivalent to that of CNS. The modification of expansive soil by hydroxy-aluminum solution primarily involved physicochemical reactions, including adsorption, ion exchange, and flocculation-agglomeration. The concentrations of K+, Na+, Ca2+, and Mg2+ of CSS all showed a significant increase. The findings suggest that CSS has a better potential for the inhibition of the swelling behavior of expansive soil. The results demonstrate the feasibility of utilizing CSS as a CNS cushion layer material for expansive soil.

Key words

expansive soil / hydroxy-aluminum solution / chemically stabilized soil / cohesive non-swelling soil / cushion layer technology

Cite this article

Download Citations
SHE Jian-bo , LI Shuai , TANG You-sheng , et al . Experimental Study of Cohesive Non-swelling Soil Stabilized with Hydroxy-Aluminum Solution for the Treatment of Expansive Soil[J]. Journal of Changjiang River Scientific Research Institute. 2025, 42(9): 131-138 https://doi.org/10.11988/ckyyb.20240765

References

[1]
MURTY V R, PRAVEEN G V. Use of Chemically Stabilized Soil as Cushion Material below Light Weight Structures Founded on Expansive Soils[J]. Journal of Materials in Civil Engineering, 2008, 20(5): 392-400.
[2]
KATTI R K. Search for Solutions to Problems in Black Cotton Soils[C]// India Geotechnical Society.Proceedings of the 20th Annual General Session of Indian Geotechnical Society. Delhi, India. December 21, 1978: 1-88.
[3]
KATTI R K, KATTI D R, KATTI A R. Behaviour of Saturated Expansive Soil and Control Methods[M]. New Delhi, India: Oxford & IBH Pub. Co. Pvt. Ltd., 1994.
[4]
KOLA S, PRASAD D S V, RAO V K L. A Study on Improvement of Expansive Soil by Using CNS (Cohesive Non-swelling Soil) Layer[J]. International Journal of Innovative Research Technology, 2016, 3(3): 54-60.
[5]
WATANABE K, NAKAJIMA S, FUJIWARA T, et al. Construction and Field Measurement of High-speed Railway Test Embankment Built on Indian Expansive Soil “Black Cotton Soil”[J]. Soils and Foundations, 2021, 61(1): 218-238.
[6]
何漓江, 刘祖德. 膨胀土路基边坡变厚式封面层稳定性实验研究[J]. 华中科技大学学报(自然科学版), 2001, 29(12):101-103.
(HE Li-jiang, LIU Zu-de. Study on Stability of Veneer Cover Soil of Variational Thickness on the Slope of Expansive Soil Subgrade[J]. Journal of Huazhong University of Science and Technology (Natural Science Edition), 2001, 29(12):101-103. (in Chinese))
[7]
何漓江, 刘祖德. 膨胀土路基边坡等厚式封面层稳定性计算方法研究[J]. 岩石力学与工程学报, 2001, 20(3): 382-385.
(HE Li-jiang, LIU Zu-de. Stability Study of Veneer Cover Soil on the Slope of Expansive Soil Subgrade[J]. Chinese Journal of Rock Mechanics and Engineering, 2001, 20(3): 382-385. (in Chinese))
[8]
孔令伟, 郭爱国, 赵颖文, 等. 荆门膨胀土的水稳定性及其力学效应[J]. 岩土工程学报, 2004, 26(6): 727-732.
(KONG Ling-wei, GUO Ai-guo, ZHAO Ying-wen, et al. Water Stability of Xiangjing Expansive Soils and Their Mechanical Effect[J]. Chinese Journal of Geotechnical Engineering, 2004, 26(6): 727-732. (in Chinese))
[9]
陈善雄, 余颂, 孔令伟, 等. 中膨胀土路堤包边方案及其试验验证[J]. 岩石力学与工程学报, 2006, 25(9):1777-1783.
(CHEN Shan-xiong, YU Song, KONG Ling-wei, et al. Wrapping Method for Middle Expansive Soil Embankment and Its Experimental Verification[J]. Chinese Journal of Rock Mechanics and Engineering, 2006, 25(9): 1777-1783. (in Chinese))
[10]
刘观仕, 孔令伟, 郭爱国, 等. 大气影响下膨胀土包边路堤变形性状研究[J]. 岩土力学, 2007, 28(7): 1397-1401.
(LIU Guan-shi, KONG Ling-wei, GUO Ai-guo, et al. Deformation Behaviors of Medium Expansive Soil Embankment Covered by Lime-treated Soils Subjected to Weather Influence[J]. Rock and Soil Mechanics, 2007, 28(7): 1397-1401. (in Chinese))
[11]
杨和平, 章高峰. 包盖法填筑膨胀土路堤的合适包边宽度[J]. 公路交通科技, 2008, 25(7): 37-42.
(YANG He-ping, ZHANG Gao-feng. Appropriate Wrapping Width of Expansive Soil Embankment Built by Enveloping Method[J]. Journal of Highway and Transportation Research and Development, 2008, 25(7): 37-42. (in Chinese))
[12]
YAO H, SHE J, LU Z, et al. Inhibition Effect of Swelling Characteristics of Expansive Soil Using Cohesive Non-swelling Soil Layer under Unidirectional Seepage[J]. Journal of Rock Mechanics and Geotechnical Engineering, 2020, 12(1): 188-196.
[13]
LU Z, TANG C, YAO H, et al. Model Tests for the Inhibition Effects of Cohesive Non-swelling Soil Layer on Expansive Soil[J]. Geomechanics and Engineering, 2022, 29(1): 91-97.
[14]
KARAMI H, POONI J, ROBERT D, et al. Use of Secondary Additives in Fly Ash Based Soil Stabilization for Soft Subgrades[J]. Transportation Geotechnics, 2021, 29: 100585.
[15]
INDIRAMMA P, SUDHARANI C, NEEDHIDASAN S. Utilization of Fly Ash and Lime to Stabilize the Expansive Soil and to Sustain Pollution Free Environment—An Experimental Study[J]. Materials Today: Proceedings, 2020, 22: 694-700.
[16]
孙世永, 姚海林, 董启朋, 等. 羟基铝及其聚合物对蒙脱土力学特性影响的试验研究[J]. 上海交通大学学报, 2013, 47(9): 1363-1366.
(SUN Shi-yong, YAO Hai-lin, DONG Qi-peng, et al. Experimental Study of Influence of Hydroxy-aluminum/Polyaluminum on Mechanical Characteristics of Montmorillonite[J]. Journal of Shanghai Jiao Tong University, 2013, 47(9): 1363-1366. (in Chinese))
[17]
YAO H, LIU L, SUN S, et al. Swelling Behavior of Montmorillonites Noncolloidally Crosslinked with Ε-Al13[J]. Soil Science Society of America Journal, 2016, 80(5):1190-1196.
[18]
ZHU R, WANG T, GE F, et al. Intercalation of both CTMAB and Al13 into Montmorillonite[J]. Journal of Colloid and Interface Science, 2009, 335(1): 77-83.
[19]
BOTTERO J Y, CASES J M, FIESSINGER F, et al. Studies of Hydrolyzed Aluminum Chloride Solutions. 1. Nature of Aluminum Species and Composition of Aqueous Solutions[J]. The Journal of Physical Chemistry, 1980, 84(22): 2933-2939.
[20]
LAMBERT J-F, PONCELET G. Acidity in Pillared Clays: Origin and Catalytic Manifestations[J]. Topics in Catalysis, 1997, 4(1/2): 43-56.
[21]
刘亮, 姚海林, 王璐, 等. 羟基铝[Al13]7+对膨胀土自由膨胀率的影响[J]. 科学技术与工程, 2020, 20(23):9282-9286.
(LIU Liang, YAO Hai-lin, WANG Lu, et al. Influence on the Hydroxy-aluminum [Al13]7+ over Free Swell of Expansive Soil[J]. Science Technology and Engineering, 2020, 20(23): 9282-9286. (in Chinese))
[22]
刘杰, 杨玉婳, 姚海林, 等. 基于不同改性方法的分散性黏土处治试验研究[J]. 岩土力学, 2020, 41(增刊1): 163-170.
(LIU Jie, YANG Yu-hua, YAO Hai-lin, et al. Experimental Study on Treatment of Dispersive Clay Based on Different Modification Methods[J]. Rock and Soil Mechanics, 2020, 41(Supp.1): 163-170. (in Chinese))
[23]
杨玉婳, 唐红, 姚海林, 等. 羟基铝改性分散性土的试验研究[J]. 人民黄河, 2021, 43(6): 136-139, 144.
(YANG Yu-hua, TANG Hong, YAO Hai-lin, et al. Experimental Study on Improvement of Dispersive Soil by Hydroxyl Aluminum[J]. Yellow River, 2021, 43(6): 136-139, 144. (in Chinese))
[24]
LIU J, CHEN P, LU Z, et al. Experimental Study on the Modification Mechanisms of Dispersive Soil Treated with Hydroxyl Aluminum[J]. Geofluids, 2022(1): 2680516.
[25]
李文宇, 江美英. 膨胀土电化学改性试验研究[J]. raybet体育在线 院报, 2018, 35(7): 100-105.
Abstract
为了研究改善膨胀土性质的方法,同时了解膨胀土改善后的性质,通过以羟基铝溶液为电解液的电化学试验方法对膨胀土的性质进行改善,将改性后的试样土分为A区(阳极区)、C区(阴极区)和M区(中间区)3个部分,并分别对3个部分试样土以及原状土进行宏观和微观试验分析。试验数据分析得到:电化学改性后的试样土的黏粒含量减少而粉粒含量增多,比表面积和孔径减小,颗粒间连接更紧密,内摩擦角增大,同时土颗粒的持水量减少,亲水性减弱,自由膨胀率大大降低。试验结果表明:膨胀土的性质变化是由[Al<sub>13</sub>]<sup>7+</sup>的离子交换和局部pH值变化等使带电土颗粒的扩散双电层变薄、颗粒间斥力变弱导致的,试样土A,C,M区的改善效果差异是受到外加电场对双电层的影响和土体微结构的各向异性等因素造成的。
(LI Wen-yu, JIANG Mei-ying. An Electrochemical Modification of Expansive Soil[J]. Journal of Yangtze River Scientific Research Institute, 2018, 35(7): 100-105. (in Chinese))
The properties of expansive soil were improved by electrochemical method with hydroxyl-aluminum solution for electrolyte. The modified soil specimens were divided into three parts: part A (anode), part C (cathode), and part M (middle). Macroscopic and microscopic tests were carried out on the three parts and natural soils. Results revealed that the clay content of modified soils decreased and the silt content increased. The specific surface area and pore size decreased, which made the contact between soil particles closer, resulting in the increase of internal friction angle. Meanwhile, the water-holding capacity of soil particles reduced, indicating that the hydrophilia weakened. Moreover, the free swell of soil samples was greatly lowered. The changes in the properties are attributed to the ion exchange of [Al<sub>13</sub>]<sup>7+</sup> and the local pH changes which thin the diffused double layer and weaken the interparticle repulsion. In addition, the effects of improvement on the three parts were different due to the influence of the applied electric field on diffused double layer and the anisotropy of soil microstructure.
[26]
马鹏, 庄艳峰, 刘志涛. 电化学法改善蒙脱土膨胀性试验研究[J]. 岩土工程学报, 2019, 41(5): 900-907.
(MA Peng, ZHUANG Yan-feng, LIU Zhi-tao. Experimental Study on Expandability of Montmorillonite Modified by Electrochemical Method[J]. Chinese Journal of Geotechnical Engineering, 2019, 41(5): 900-907. (in Chinese))
[27]
JTG 3430—2020, 公路土工试验规程[S]. 北京: 人民交通出版社, 2020.
(JTG 3430—2020, Test Methods of Soils for Highway Engineering[S]. Beijing: China Communication Press, 2020. (in Chinese))
[28]
HACH C. Water Analysis Handbook[M].5th ed. Loveland,Colorado,USA: Hach Company, 2009.
[29]
GB/T 50145—2007, 土的工程分类标准[S]. 北京: 中国计划出版社, 2008.
(GB/T 50145—2007, Standard for Engineering Classification of Soil[S]. Beijing: China Planning Press, 2008. (in Chinese))
[30]
TURKOZ M, SAVAS H, ACAZ A, et al. The Effect of Magnesium Chloride Solution on the Engineering Properties of Clay Soil with Expansive and Dispersive Characteristics[J]. Applied Clay Science, 2014, 101: 1-9.
[31]
丁小刚, 余云燕, 蔺文博, 等. 非饱和弱膨胀土土-水特征曲线拟合与渗透系数模型预测[J]. 中南大学学报(自然科学版), 2022, 53(1): 361-370.
(DING Xiao-gang, YU Yun-yan, LIN Wen-bo, et al. Fitting of Soil-water Characteristic Curve and Prediction of Permeability Coefficient Model of Unsaturated Weak Expansive Soil[J]. Journal of Central South University (Science and Technology), 2022, 53(1): 361-370. (in Chinese))
[32]
GB 50112—2013,膨胀土地区建筑技术规范[S]. 北京: 中国建筑工业出版社, 2013.
(GB 50112—2013,Technical Code for Buildings in Expansive Soil Regions[S]. Beijing: China Architecture & Building Press, 2013. (in Chinese))
PDF(7524 KB)

Accesses

Citation

Detail

Sections
Recommended

/

Baidu
map