Progress in the Research of Factors Affecting the Adsorption of Phosphorus by Mineral Clay and Iron Zirconium Compounds

FENG Xue, ZHANG Zheng, WANG Qian-cheng, HOU Gui-bao

Journal of Changjiang River Scientific Research Institute ›› 2017, Vol. 34 ›› Issue (3) : 14-19.

PDF(1254 KB)
PDF(1254 KB)
Journal of Changjiang River Scientific Research Institute ›› 2017, Vol. 34 ›› Issue (3) : 14-19. DOI: 10.11988/ckyyb.20151031
WATER RESOURCES AND ENVIRONMENT

Progress in the Research of Factors Affecting the Adsorption of Phosphorus by Mineral Clay and Iron Zirconium Compounds

  • FENG Xue1, ZHANG Zheng2, WANG Qian-cheng3, HOU Gui-bao1
Author information +
History +

Abstract

Removing phosphorus from water through adsorption is highly efficient with low energy consumption. In this article, the characteristics of adsorbents and the adsorption mechanisms of metal oxides, clay mineral, and activated carbon are introduced. The effects of reaction temperature, reaction time, pH value, and coexisting ions on the adsorption process of mineral clay and iron zirconium compounds are expounded: reaction temperature mainly affects the molecular heat movement, which further affects the adsorption effect; a certain reaction time is always needed to reach the optimum effect; pH value mainly has an influence on ion concentration, ion type and ion reaction; coexisting ions could improve the Coulomb force and the competitiveness of phosphate’s active site. Moreover, the effects of adsorbent amount, phosphorus’ initial concentration, electrolyte and adsorbent’s particle size on the phosphorus adsorption are also described. Modified materials and composite materials are research focuses in the future.

Key words

mineral clay / iron oxides / zirconium iron compounds / adsorption / phosphate

Cite this article

Download Citations
FENG Xue, ZHANG Zheng, WANG Qian-cheng, HOU Gui-bao. Progress in the Research of Factors Affecting the Adsorption of Phosphorus by Mineral Clay and Iron Zirconium Compounds[J]. Journal of Changjiang River Scientific Research Institute. 2017, 34(3): 14-19 https://doi.org/10.11988/ckyyb.20151031

References

[1] 高思佳, 王昌辉, 裴元生. pH对活化前后废弃铁铝泥吸附不同种磷动力学的影响[J]. 环境工程学报, 2013,7(9):3263-3269.
[2] 吴丽萍, 徐晓瑛, 文科军,等. 不同粒径炉渣对磷的静态吸附[J]. 环境工程学报, 2014, 9(9):3933-3938.
[3] 梁丽珍, 牛俊玲. 改性碎砖对磷的吸附性能研究[J]. 环境工程, 2014, (10):38-40.
[4] 周 乐, 徐龙君, 李 礼,等. 改性二次锶渣吸附去除废水中的磷[J]. 环境工程学报, 2013, 7(10):3967-3971.
[5] 武轩韵, 栾亚宁, 龚小强,等. 3种基质对污水中总磷的吸附性能[J]. 环境工程学报, 2015, 1(1):257-263.
[6] 姜灵彦, 高军侠, 李庆召. 活化橘皮渣对废水中磷的吸附效果研究[J]. 河南农业科学, 2014, 43(8):68-71.
[7] 马啸宙, 魏东洋, 马宏林,等. 基于给水污泥吸附水溶液中磷的影响因素[J]. 环境工程学报, 2015,9(8):3659-3666.
[8] 张 璐, 贾 丽, 陆文龙,等. 不同碳化温度下玉米秸秆生物炭的结构性质及其对氮磷的吸附特性[J]. 吉林大学学报(理学版), 2015, 4(4):802-808.
[9] 赵 娟, 李远文, 杨耐德,等. 改性牡蛎壳对废水中磷吸附性能的研究[J]. 化工新型材料, 2014, (3):154-156.
[10]王春丽, 吴俊奇, 宋永会,等. 活化赤泥颗粒吸附除磷的效能与机制研究[J]. 环境工程技术学报, 2015, 5(2):49-50.
[11]甘 莉, 曹 丹, 金晓英,等. 离子型表面活性剂改性绿色合成单分散纳米氧化铁的制备及其吸附磷的性能[J]. 环境科学学报, 2015, 35(8):2442-2449.
[12]李 琦, 付格娟, 李剑超. LDH的制备及其对水环境中低含量磷的吸附研究[J]. 水处理技术, 2013, 39(8):47-51.
[13]黄大成, 王惠松, 邹亚娟,等. 常压制备秸秆活性炭对水溶液中磷元素的吸附[J]. 环境工程学报, 2015, 9(3):1183-1188.
[14]李 倩, 燕晓莹. 超声处理鸡蛋壳对废水中磷吸附的影响[J]. 贵州农业科学, 2015, (3):177-179.
[15]温秀芹. 火法改性粉煤灰对含磷废水吸附性能的研究[J]. 广东化工, 2015, 42(3):59-60.
[16]吴 燕, 安树林. 废水除磷方法的现状与展望[J]. 天津工业大学学报, 2001,20(1):74-78.
[17]JOSSON A S. Fundamental Principles of Ultrafiltration[J]. Chemical Engineering and Processing: Process Intensification, 1990, 27(2): 67-81.
[18]刘 晓, 翟 梅, 曹国凭,等. 钢渣滤料的制备及其吸附除磷性能[J]. 河北联合大学学报(自然科学版), 2014,(1):13-17.
[19]付海曼, 贾黎明. 土壤对氮、磷吸附/解吸附特性研究进展[J]. 中国农学通报, 2009, 25(21):198-203.
[20]辛 杰, 裴元生, 王 颖,等. 几种吸附材料对磷吸附性能的对比研究[J]. 环境工程, 2011, 29(4):30-34.
[21]张学清, 项金钟, 胡永茂,等. 天然沸石对磷的吸附研究[J]. 云南大学学报(自然科学版), 2011,33(6):676-682.
[22]LI G, GAO S, ZHANG G, et al. Enhanced Adsorption of Phosphate from Aqueous Solution by Nanostructured Iron(III)-copper(II) Binary Oxides[J]. Chemical Engineering Journal, 2014, 235(1):124-131.
[23]YOON S Y, LEE C G, PARK J A, et al. Kinetic, Equilibrium and Thermodynamic Studies for Phosphate Adsorption to Magnetic Iron Oxide Nanoparticles[J]. Chemical Engineering Journal, 2014, 236(2):341-347.
[24]唐朝春, 陈惠民, 刘 名,等. ZnAl和MgAl水滑石吸附废水中磷的研究进展[J]. 化工进展, 2015, 34(1):245-251.
[25]李 洁, 陈繁荣. 4种矿物材料对磷的吸附特性研究[J]. 安徽农业科学, 2015, 43(19):237-240.
[26]石 岩, 郭汶俊, 郭东鑫,等. 人造沸石对含磷废水的吸附实验研究[J]. 华北水利水电大学学报:自然科学版, 2015, 36(1):90-92.
[27]王 帅, 周震峰, 刁玲玲. 沸石对水中磷吸附性能的初步研究[J]. 环境科学导刊, 2014, 33(5):52-56.
[28]商丹红, 王 琦, 张志生. Mg/Fe水滑石吸附水中磷的动力学及热力学研究[J]. 环境污染与防治, 2015, 37(4):47-52.
[29]刘国, 李 军, 杨 衔,等. 铁镁铝三元类水滑石对磷的吸附特性研究[J]. 工业水处理, 2015, 35(1):62-64.
[30]HUANG W Y, LI D, LIU Z Q, et al. Kinetics, Isotherm, Thermodynamic, and Adsorption Mechanism Studies of La(OH)3-modified Exfoliated Vermiculites as Highly Efficient Phosphate Adsorbents[J]. Chemical Engineering Journal, 2014, 236(2):191-201.
[31]YUAN X L, XIA W T, AN J, et al. Removal of Phosphate Anions from Aqueous Solutions Using Dolomite as Adsorbent[J]. Advanced Materials Research, 2013, 864:1454-1457.
[32]YUAN X L, XIA W T. Removal of Phosphate Anions from Wastewater by Wasted Low Grade Iron Ore with High Phosphorus Adsorbent[J]. Advanced Materials Research, 2013, 803:127-130.
[33]YAO Y L, LU C Y, GUAN W S, et al. Removal of Phosphate Species from Solution by Adsorption onto Red and Grey Ceramic Clay Used as Adsorbent[J]. Applied Mechanics & Materials, 2014, 675-677:434-439.
[34]FUMIHIKO O, HISATO T, MOE K, et al. Characteristics of Granular Boehmite and Its Ability to Adsorb Phosphate from Aqueous Solution.[J]. Chemical & Pharmaceutical Bulletin, 2012, 60(8):985-988.
[35]张翠玲, 党 瑞, 贺建栋,等. 白银天然沸石对磷的吸附机理及性能研究[J]. 环境科学与管理, 2014, 39(12):104-108.
[36]李 辉, 左金龙, 王军霞. 天然沸石及其改性对污水中磷的吸附[J]. 哈尔滨商业大学学报(自然科学版), 2015,31(3):311-314.
[37]陆燕勤, 朱 丽, 何昭菊,等. 沸石负载氧化铁吸附剂吸附除磷研究[J]. 环境工程, 2015, 33(4):48-52.
[38]潘维煜. 浅析无机改性煤矸石对磷的吸附[J]. 科技创新与应用, 2014, (1):32-33.
[39]李 晶, 何 欣, 张 瑶,等. 水滑石除磷的吸附动力学研究[J]. 材料导报, 2014, 28(22):85-88.
[40]郑丽英. 粉煤灰吸附去除城区景观水体中磷的试验研究[J]. 广州化工, 2014, 41(24):95-96.
[41]李 艳, 赵孝梨, 黄玉明. 磁性纳米Fe3O4对水中磷的吸附去除研究[J]. 西南大学学报:自然科学版, 2013, 35(5):127-130.
[42]SHEN H, WANG Z, ZHOU A, et al. Adsorption of Phosphate onto Amine Functionalized Nano-sized Magnetic Polymer Adsorbents: Mechanism and Magnetic Effects[J]. Rsc Advances, 2015, 5:22080-22090.
[43]LIN Y F, CHEN H W, CHEN Y C, et al. Application of Magnetite Modified with Polyacrylamide to Adsorb Phosphate in Aqueous Solution[J]. Journal of the Taiwan Institute of Chemical Engineers, 2013, 44(1):45-51.
[44]LIN Ya-fen, CHEN Hua-wei, CHANG Chia-chi, et al. Application of Magnetite Modified with Aluminum/silica to Adsorb Phosphate in Aqueous Solution[J]. Journal of Chemical Technology & Biotechnology, 2011, 86(11):1449-1456.
[45]彭晓丽, 张蔚霞, 徐 芳. 磁性Fe3O4/Beta沸石复合材料制备及其水体磷污染物吸附行为研究[J]. 化学世界, 2013, 54(3):145-147.
[46]WU Q,YOU R R,WU Q P, et al. Equilibrium and Kineticsstudies of Phosphate Removal from Solution onto a Hydrothermally Modified Al-Si-Fe-Ca Composite Adsorbent[J]. Energy, Environment and Functional Materials, 2014, 787: 128-134
[47]CHEN T C, HUANG G H, LIU C H, et al. Novel Effective Waste Iron Oxide-coated Magnetic Adsorbent for Phosphate Adsorption[J]. Desalination & Water Treatment, 2014, 52(4):766-774.
[48]ZELMANOV G, SEMIAT R. Phosphate Removal from Water and Recovery Using Iron (Fe+3)Oxide/Hydroxide Nanoparticles-based Agglomerates Suspension (AggFe) as Adsorbent[J]. Environmental Engineering & Management Journal, 2011, 10(12):1923-1933.
[49]CHEN T C, SHIH Y J, CHANG C C, et al. Novel Adsorbent of Removal Phosphate from TFT LCD Wastewater[J]. Journal of the Taiwan Institute of Chemical Engineers, 2013, 44(1):61-66.
[50]AWUAL M R, SHENASHEN M A, JYO A, et al. Preparing of Novel Fibrous Ligand Exchange Adsorbent for Rapid Column-mode Trace Phosphate Removal from Water[J]. Journal of Industrial & Engineering Chemistry, 2014, 20(5):2840-2847.
[51]LIN K Y A, CHEN S Y, JOCHEMS A P. Zirconium-based Metal Organic Frameworks: Highly Selective Adsorbents for Removal of Phosphate from Water and Urine[J]. Materials Chemistry & Physics, 2015, 160:168-176.
[52]TANG Y, ZONG E, WAN H, et al. Zirconia Functionalized SBA-15 as Effective Adsorbent for Phosphate Removal[J]. Microporous & Mesoporous Materials, 2012, 155(6):192-200.
[53]L J, LIU H, LIU R, et al. Adsorptive Removal of Phosphate by a Nanostructured Fe-Al-Mn Trimetal Oxide Adsorbent[J]. Powder Technology, 2013, 233(1):146-154.
[54]赵 维, 陈佑宁. 磁性类水滑石的制备和吸附水中磷的研究[J]. 应用化工, 2013, 03(3):450-452.
[55]DAI J, YANG H, HAN Y, et al. Phosphate Adsorption from Aqueous Solutions by Disused Adsorbents: Chitosan Hydrogel Beads after the Removal of Copper(II)[J]. Chemical Engineering Journal, 2011, 166(3):970-977.
PDF(1254 KB)

Accesses

Citation

Detail

Sections
Recommended

/

Baidu
map