Chloride Ion Diffusion in Aeolian Sand Concrete under Salt Freezing

DONG Wei, XIAO Yang, SU Ying

Journal of Changjiang River Scientific Research Institute ›› 2021, Vol. 38 ›› Issue (2) : 125-130.

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Journal of Changjiang River Scientific Research Institute ›› 2021, Vol. 38 ›› Issue (2) : 125-130. DOI: 10.11988/ckyyb.20191005
HYDRAULIC STRUCTURE AND MATERIAL

Chloride Ion Diffusion in Aeolian Sand Concrete under Salt Freezing

  • DONG Wei, XIAO Yang, SU Ying
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Abstract

Concrete specimens with different aeolian sand content (mass substitution rate 0%, 25%, 50%, 75%, 100%) were prepared to conduct experimental research on the effect of aeolian sand content on chloride ion diffusion in concrete under cyclic freezing and thawing of chloride salt. The free chloride ion concentration and total chloride ion concentration in concrete with different aeolian sand contents under salt freezing environment were determined by chemical analysis method, and the relative chloride ion binding coefficient and chloride ion diffusion coefficient of aeolian sand concrete were calculated. Results revealed that the free chloride ion concentration declined at first but then increased with the augment of aeolian sand content, while gradually increased with the proceeding of cyclic freezing and thawing. The binding performance of aeolian sand concrete showed good Langumir nonlinear adsorption and had no direct relationship with freeze-thaw cycles. When the content of aeolian sand was 25%, the relative chloride ion binding coefficient was the smallest. The chloride ion diffusion coefficient hit the lowest value under the same freeze-thaw cycles. Cyclic freezing and thawing had little effect on the diffusion rate of chloride ion in concrete with large content of aeolian sand. The diffusion coefficient of chloride ion of the test group with 100% aeolian sand content decreased with the proceeding of freeze-thaw cycles, displaying good resistance to chloride ion erosion. Proper amount of aeolian sand could better resist chloride ion invasion, and a large amount of aeolian sand could boost the frost resistance of concrete under chloride salt erosion.

Key words

aeolian sand concrete / salt freezing / chloride ion / diffusion coefficient / cyclic freezing and thawing

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DONG Wei, XIAO Yang, SU Ying. Chloride Ion Diffusion in Aeolian Sand Concrete under Salt Freezing[J]. Journal of Changjiang River Scientific Research Institute. 2021, 38(2): 125-130 https://doi.org/10.11988/ckyyb.20191005

References

[1] 吴俊臣, 申向东, 董 伟, 等. 风积沙水泥基混凝土的工程应用与耐久性能研究现状[J]. 硅酸盐通报,2015,34(10):2845-2850.
[2] 王晨飞, 牛荻涛, 焦俊婷. 海洋潮汐环境纤维混凝土中氯离子迁移规律研究[J]. 混凝土,2017(1):20-23.
[3] DONG Wei, SHEN Xiang-dong, XUE Hui-jun, et al. Research on the Freeze-Thaw Cyclic Test and Damage Model of Aeolian Sand Lightweight Aggregate Concrete[J]. Construction and Building Materials, 2016, 123: 792-799.
[4] 吴俊臣, 申向东, 郝贠洪. 冻融循环次数与风积沙掺量对混凝土氯离子扩散的影响[J]. 硅酸盐通报,2017,36(11):3784-3790.
[5] 李 强, 余红发, 张立明. 冻融循环对粉煤灰混凝土氯离子扩散系数的影响[J]. 应用基础与工程科学学报,2015,23(3):622-628.
[6] 乔宏霞, 梁金科, 李元可,等. 石粉对混凝土力学性能及氯离子扩散系数影响[J]. 硅酸盐通报,2019,38(2):431-435,439.
[7] TUUTTI K. Corrosion of Steel in Concrete[R]. Stockholm: Swedish Cement and Concrete Research Institute, 1982.
[8] 孙丛涛, 宋 华, 牛荻涛,等. 粉煤灰混凝土的氯离子结合性能[J]. 建筑材料学报,2016,19(1):35-39.
[9] 吴俊臣, 申向东. 风积沙混凝土的抗冻性与冻融损伤机理分析[J]. 农业工程学报,2017,33(10):184-190.
[10] LI Gen-feng, SHEN Xiang-dong. A Study of the Deterioration Law and Mechanism of Aeolian-sand Powder Concrete in the Coupling Environments of Freeze-Thaw and Carbonization[J]. Journal of the Ceramic Society of Japan, 2019, 127(8): 551-563.
[11] LI Gen-feng, SHEN Xiang-dong. A Study of the Durability of Aeolian Sand Powder Concrete Under the Coupling Effects of Freeze-Thaw and Dry-Wet Conditions[J]. Journal of the Minerals, Metals and Materials Society, 2019, 71(6): 1962-1974.
[12] 刘 军, 董必钦, 邢 锋, 等. 海砂氯离子与水泥胶体结合的模拟实验与结合机理[J]. 硅酸盐学报,2009,37(5):862-866,876.
[13] TANG L, NILSSON L O. Chloride Binding Capacity and Binding Isotherms of OPC Pastes and Mortars[J]. Cement and Concrete Research,1993, 23(2): 247-253.
[14] SERGI W, YU S W, PAGE C L. Diffusion of Chloride and Hydroxylions in Cementitious Materials Exposed to a Saline Environment[J]. Magazine of Concrete Research, 1992, 44(158): 63-69.
[15] 孙丛涛, 牛荻涛. 冻融环境混凝土氯离子扩散性能试验研究[J]. 硅酸盐通报,2014,33(8):1863-1869.
[16] WANG Yuan-zhan, FU Kun. Comparisons of Instantaneous Chloride Diffusion Coefficients Determined by RCM Method and Chloride Natural Diffusion Test[J]. Construction and Building Materials, 2019, 223: 595-604.
[17] YU Hong-fa,TAN Yong-shan,FENG Tao-tao.Study of Temporal Change in Chloride Diffusion Coefficient of Concrete[J]. ACI Materials Journal,2019,116(1):103-112.
[18] 张立明, 余红发. 干湿循环次数对氯离子扩散系数的影响[J]. 湖南大学学报(自然科学版),2014,41(3):26-30.
[19] HONG K, HOOTONR D. Effects of Cyclic Chloride Exposure on Penetration of Concrete Cover[J]. Cement and Concrete Research, 1999, 29(9): 1379-1386.
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